I believe it's Seth Armstrong who has been there since the 70s.
The character of Jack has been in it the longest but was played by a different actor and left for a number of years anyway. Clive Hornby (the current Jack) has been in the role since 1980.
Alan Turner joined in the very early 80s (82?), Eric Pollard in 86, Zoe in 89. I THINK they're the only true old-skool characters left and everyone is post-planecrash (except a couple like Viv, who were there only a short while before the crash anyway), though I'm not certain.