They won't have the mentors singing with the acts thing again, as Nicole would have to sing twice (assuming James and Jahmene both make it).
I also can't see Gary wanting to sing with Christopher.
Instead I think it will be:
Christopher - someone like SuBo or Elaine Page, an older female vocalist
Union J - Olly Murs maybe? Someone young and fun.
Jahmene - female soul vocalist. Jennifer Hudson is the obvious choice but I could see him getting Beyonce if they want him to win. Or Kelly Clarkson maybe? I know she's not soul but that could work anyway.
James Arthur - I really don't know about this one.