Vodafone does have access to Telecom DE but have an aggressive steering platform in place which tries its best to stop your handset using a non-Vodafone network.
The phone will connect to Vodafone DE by default (if available) as the Voda SIM will have Voda DE saved as a 'preferred network'. On connection, the Voda UK network will receive a message from Voda DE asking for authentication, and this will be instantly granted.
On the other hand - if, say, the phone tries to connect to Telecom; Voda UK will not authenticate the connection. After 30 seconds or so the phone gives up, by which time the system hopes you'll have moved position and have Voda DE coverage. However, if the handset tries 3 times in a row to connect to Telecom, then the connection will be allowed.
The idea is Voda don't want you to use a non-preferred network unless you literally have no other option, in which case they settle for the smaller revenue from a non-preferred partner than no revenue at all.
If you're manually selecting a network it often returns an error or 'no access'. Keep persisting (or on iPhone leave it alone on 'no service' for a while) and magically it will connect

O2 employ similar wily tricks.